CeO2(111) electronic reducibility tuned by ultra-small supported bimetallic Pt

CeO2(111) electronic reducibility tuned by ultra-small supported bimetallic Pt–Cu clusters

Published:2019 Issue:28 Volume:21 Page:15286-15296
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Paz-Borbón Lauro Oliver¹²³⁴^ORCID,Buendía Fernando¹²³⁴^ORCID,Garzón Ignacio L.¹²³⁴^ORCID,Posada-Amarillas Alvaro⁵⁶⁷⁴^ORCID,Illas Francesc⁸⁹¹⁰¹¹^ORCID,Li Jun¹²¹³¹⁴¹⁵¹²^ORCID

Affiliation:

1. Instituto de Física

2. Universidad Nacional Autónoma de México

3. 01000 CDMX

4. Mexico

5. Departamento de Investigación en Física

6. Universidad de Sonora

7. 83000 Hermosillo

8. Departament de Ciència de Materials i Química Física & Institut de Quιmica Teòrica i Computacional (IQTCUB)

9. de la Universitat de Barcelona

10. 08028 Barcelona

11. Spain

12. Department of Chemistry

13. Tsinghua University

14. Beijing 100084

15. China

Abstract

Controlling Ce⁴⁺ to Ce³⁺ electronic reducibility in a rare-earth binary oxide such as CeO₂ has enormous applications in heterogeneous catalysis, where a profound understanding of reactivity and selectivity at the atomic level is yet to be reached.

Funder

National Natural Science Foundation of China

Consejo Nacional de Ciencia y Tecnología

Dirección General de Asuntos del Personal Académico, Universidad Nacional Autónoma de México

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CP/C9CP01772K

Reference89 articles.

1. The Impact of Nanoscience on Heterogeneous Catalysis