Isolable fluorinated triphenylmethyl cation salts of [HCB11Cl11]−: demonstration of remarkable hydride affinity-Reference-Cited by-同舟云学术

Isolable fluorinated triphenylmethyl cation salts of [HCB₁₁Cl₁₁]⁻: demonstration of remarkable hydride affinity

Published:2022 Issue:17 Volume:13 Page:4972-4976
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Gunther S. Olivia¹,Lee Chun-I¹,Song Ellen¹,Bhuvanesh Nattamai¹,Ozerov Oleg V.¹^ORCID

Affiliation:

1. Department of Chemistry, Texas A&M University, 3255 TAMU, College Station, Texas 77842, USA

Abstract

Hexakis(meta-fluoro)substituted triphenylmethyl cation (F6Tr+) was isolated with a carborane partner anion. Its significantly higher hydride affinity compared to the parent (Tr+) allows it to abstract hydrides from a variety of C(sp3)–H bonds.

Funder

U.S. Naval Research Laboratory

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D1SC05936J

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