Mechanistic insights into the in vitro metal-promoted oxidation of (di)azine hydroxamic acids: evidence of HNO release and N,O-di(di)azinoyl hydroxylamine intermediate

Author:

Carvalho Edinilton Muniz12345ORCID,Rechignat Lionel12345,Sousa Eduardo Henrique Silva de678910ORCID,Lopes Luiz Gonzaga de França678910ORCID,Chauvin Remi12345ORCID,Bernardes-Génisson Vania12345ORCID

Affiliation:

1. CNRS, Laboratoire de Chimie de Coordination

2. LCC

3. UPR 8241

4. F-31077 Toulouse

5. France

6. Laboratório de Bioinorgânica

7. Universidade Federal do Ceará

8. Departamento de Química Orgânica e Inorgânica

9. Fortaleza

10. Brazil

Abstract

HNO is released through a one-electron oxidation of the hydroxamic acid along with the N,O-di(di)azinoylhydroxylamine intermediate.

Funder

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Fundação Cearense de Apoio ao Desenvolvimento Científico e Tecnológico

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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