Enhanced dielectricity coupled to spin-crossover in a one-dimensional polymer iron(ii) incorporating tetrathiafulvalene-Reference-Cited by-同舟云学术

Enhanced dielectricity coupled to spin-crossover in a one-dimensional polymer iron(ii) incorporating tetrathiafulvalene

Published:2020 Issue:24 Volume:11 Page:6229-6235
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Qiu Ya-Ru¹²³⁴⁵,Cui Long¹²³⁴⁵,Cai Pei-Yu¹²³⁴⁵,Yu Fei¹²³⁴⁵^ORCID,Kurmoo Mohamedally¹²³⁴⁵^ORCID,Leong Chanel F.⁶⁷⁸⁹,D'Alessandro Deanna M.⁶⁷⁸⁹^ORCID,Zuo Jing-Lin¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory of Coordination Chemistry

2. School of Chemistry and Chemical Engineering

3. Collaborative Innovation Center of Advanced Microstructures

4. Nanjing University

5. Nanjing 210023

6. School of Chemistry

7. The University of Sydney

8. Sydney

9. Australia

Abstract

A concerted bending–flattening motion of the redox-active TTF within constructed one-dimensional Fe^II–TTF–Schiff-base chain with bridging 4,4′-bpy enhances the dielectric constant coupled to its spin-crossover transition above room temperature.

Funder

National Natural Science Foundation of China

National Basic Research Program of China

Australian Research Council

Centre National de la Recherche Scientifique

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC02388D

Reference63 articles.