Unprecedented superstructure in the type I family of clathrates-Reference-Cited by-同舟云学术

Unprecedented superstructure in the type I family of clathrates

Published:2021 Issue:100 Volume:57 Page:13780-13783
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Yox Philip¹²,Lebedev Oleg I.³,Donadio Davide⁴^ORCID,Kovnir Kirill¹²^ORCID

Affiliation:

1. Department of Chemistry, Iowa State University, Ames, IA 50011, USA

2. Ames Laboratory, U.S. Department of Energy, Ames, IA 50011, USA

3. Laboratoire Crismat, Ensicaen, CNRS UMT 6508, 6 Boulevard du Marechal Juin, F-14050 Caen, France

4. University of California, Davis, Davis, CA 95616, USA

Abstract

Chemical bonding preferences to optimize Ba–Au, Au–As, and As–As interactions lead to a new superstructure in type I clathrate Ba8Au16As30, which exhibits ultralow thermal conductivity.

Funder

Office of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D1CC05167A

Reference24 articles.

1. G.Nolas , The Physics and Chemistry of Inorganic Clathrates , Springer , Netherlands , 1 edn, 2014

2. Clathrate thermoelectrics

3. Unconventional Clathrates with Transition Metal–Phosphorus Frameworks

4. Ba8Cu16P30 - eine neue tern�re Variante des Clathrat I-Strukturtyps

5. Thermoelectric properties of a clathrate compound Ba8Cu16P30

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