Lithiation of palladated dihydropentacene: a new route for the introduction of substituents from both of electrophiles and nucleophiles to pentacene-Reference-Cited by-同舟云学术

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Lithiation of palladated dihydropentacene: a new route for the introduction of substituents from both of electrophiles and nucleophiles to pentacene

Published:2018 Issue:10 Volume:54 Page:1265-1268
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Wang Yanqing¹²³⁴,Nakajima Kiyohiko⁵⁶⁷⁸⁴,Song Zhiyi¹²³⁴^ORCID,Takahashi Tamotsu¹²³⁴^ORCID

Affiliation:

1. Institute for Catalysis

2. Hokkaido University

3. Kita-ku

4. Japan

5. Department of Chemistry

6. Aichi University of Education

7. Igaya

8. Kariya

Abstract

A lithiated-palladated dihydropentacene complex was treated with electrophiles and nucleophiles successively to give substituted pentacene derivatives.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C7CC09535J

Reference39 articles.

1. E. Negishi , Handbook of Organopalladium Chemistry for Organic Synthesis , John Wiley & Sons , New York , 2002

2. The reaction of σ-vinylpalladium complexes with alkyllithiums. Stereospecific syntheses of olefins from vinyl halides and alkyllithiums

3. Position-specific alkylation of lithio-1-trimethylsilylpropyne, a useful new route to acetylenes and 1, 5-dienes

4. The palladium(II) induced alkylation of styrenes. Kinetics, stereochemistry, and mechanism

5. Palladium catalysed allylic substitution via in situ activation of allylic alcohols

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