Rhodium(i)-catalyzed asymmetric [4 + 2] cycloaddition reactions of 2-alkylenecyclobutanols with cyclic enones through C–C bond cleavage: efficient access totrans-bicyclic compounds-Reference-Cited by-同舟云学术

Rhodium(i)-catalyzed asymmetric [4 + 2] cycloaddition reactions of 2-alkylenecyclobutanols with cyclic enones through C–C bond cleavage: efficient access totrans-bicyclic compounds

Published:2018 Issue:7 Volume:9 Page:1873-1877
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Zheng Xinxin¹²³⁴^ORCID,Guo Rui⁵⁶⁷⁸⁹^ORCID,Zhang Guozhu⁵⁶⁷⁸⁹^ORCID,Zhang Dayong¹²³⁴

Affiliation:

1. Institute of Pharmaceutical Science

2. China Pharmaceutical University

3. Nanjing

4. P. R. China

5. State Key Laboratory of Organometallic Chemistry

6. Center for Excellence in Molecular Synthesis

7. Shanghai Institute of Organic Chemistry

8. Chinese Academy of Sciences

9. Shanghai 200032

Abstract

We report a rhodium-catalyzed asymmetric formal intermolecular [4 + 2] cycloaddition reaction of 2-alkylenecyclobutanols with α,β-unsaturated cyclic ketones leading to synthetically usefultrans-bicyclic molecules.

Funder

National Natural Science Foundation of China

Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/SC/C7SC04784C

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