Highly polar stacking interactions wrap inorganics in organics: lone-pair–π-hole interactions between the PdO4 core and electron-deficient arenes-Reference-Cited by-同舟云学术

Highly polar stacking interactions wrap inorganics in organics: lone-pair–π-hole interactions between the PdO4 core and electron-deficient arenes

Published:2021 Issue:23 Volume:8 Page:4965-4975
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Torubaev Yury V.¹^ORCID,Skabitsky Ivan V.¹,Rozhkov Anton V.²^ORCID,Galmés Bartomeu³,Frontera Antonio³^ORCID,Kukushkin Vadim Yu.²⁴^ORCID

Affiliation:

1. N. S. Kurnakov Institute of General and Inorganic Chemistry, of Russian Academy of Sciences, Moscow, 119991 Russian Federation

2. Institute of Chemistry, Saint Petersburg State University, Universitetskaya Nab. 7/9, Saint Petersburg, 199034 Russian Federation

3. Department of Chemistry, Universitat de les IllesBalears, 07122 Palma de Mallorca, Baleares, Spain

4. Institute of Chemistry and Pharmaceutical Technologies, Altai State University, 656049 Barnaul, Russian Federation

Abstract

Each PdO4 plane of Pd3(OAc)6 behaved as a 5-center nucleophile (O lone pairs and the dz2-PdII orbital) that interacts with π-donating arenes to afford highly polar circular stacking, where organics wrapped inorganics.

Funder

Federación Española de Enfermedades Raras

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/QI/D1QI01067K

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