Amorphous calcium carbonate monohydrate containing a defect hydrate network by mechanochemical processing of mono-hydrocalcite using ethanol as auxiliary solvent

Author:

Maslyk Marcel1,Mondeshki Mihail1ORCID,Tremel Wolfgang1ORCID

Affiliation:

1. Department Chemie, Johannes Gutenberg-Universität, Duesbergweg 10-14, D-55099 Mainz, Germany

Abstract

Calcium carbonate monohydrate-like ACC was made by ball-milling with ethanol as auxiliary solvent. IR and solid-state NMR, diffraction and total scattering show that defects of the hydrate network due to partial displacement of water by ethanol are crucial for amorphization.

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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