Reversible photo-isomerization of cis-[Pd(L-κS,O)2] (HL = N,N-diethyl-N′-1-naphthoylthiourea) to trans-[Pd(L-κS,O)2] and the unprecedented formation of trans-[Pd(L-κS,N)2] in solution
Author:
Affiliation:
1. Department of Chemistry and Polymer Science
2. Stellenbosch University
3. South Africa
4. Centre for Hyperpolarisation in Magnetic Resonance
5. Department of Chemistry
6. York Science Park
7. University of York
8. York YO10 5NY
Abstract
Ex-situ with polychromatic or in-situ laser light irradiation of solutions of pure cis-[Pd(L-κS,O)2] leads to the formation of trans-[Pd(L-κS,O)2] species that in the dark reverts via an unprecedented trans-[Pd(L-κS,N)2] cleanly to the cis-[Pd(L-κS,O)2].
Funder
National Research Foundation
Universiteit Stellenbosch
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT03672E
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