Impact of rotamer diversity on the self-assembly of nearly isostructural molecular semiconductors

Author:

McDowell Caitlin12345,Narayanaswamy Kamatham678,Yadagiri Bommaramoni678,Gayathri Thumuganti678,Seifrid Martin12345,Datt Ram91011128ORCID,Ryno Sean M.1314155ORCID,Heifner Michael C.1314155,Gupta Vinay91011128,Risko Chad1314155ORCID,Singh Surya Prakash678ORCID,Bazan Guillermo C.12345ORCID

Affiliation:

1. Department of Chemistry and Biochemistry

2. Center for Polymers and Organic Solids

3. University of California

4. Santa Barbara

5. USA

6. Inorganic and Physical Chemistry Division

7. CSIR-Indian Institute of Chemical Technology

8. India

9. Organic and Hybrid Solar Cells

10. Physics of Energy Harvesting Division

11. CSIR-National Physical Laboratory

12. New Delhi-110012

13. Department of Chemistry & Center for Applied Energy Research

14. University of Kentucky

15. Lexington

Abstract

Switching bithiophene for thienothiophene reduces the number of rotational conformations, facilitating self-assembly with minimal effects on the electronic structure.

Funder

Indo-US Science and Technology Forum

Office of Naval Research

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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