Rh(<scp>iii</scp>)-catalyzed aldehydic and aryl C–H alkylation with cyclopropanols <i>via</i> C–H/C–C bond activation-Reference-Cited by-同舟云学术

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Rh(iii)-catalyzed aldehydic and aryl C–H alkylation with cyclopropanols via C–H/C–C bond activation

Published:2024 Issue: Volume: Page:
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Dash Om Prakash¹,Garg Divya¹,Volla Chandra M. R.¹^ORCID

Affiliation:

1. Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai-400076, India

Abstract

Herein, we developed an efficient C–H alkylation of 2-aminobenzaldehydes and anilines employing cyclopropanol as an alkylating agent under Rh(iii)-catalysis for accessing a wide range of 1,4-diketones and β-aryl ketones in good to excellent yields.

Funder

Science and Engineering Research Board

Council of Scientific and Industrial Research, India

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC03797A

Reference30 articles.

1. Development of a Concise Synthesis of Ouabagenin and Hydroxylated Corticosteroid Analogues

2. Total Synthesis of Herquline B and C

3. Synthetic approaches to 1,4-dicarbonyl compounds

4. A Regio- and Stereoselective ω-Transaminase/Monoamine Oxidase Cascade for the Synthesis of Chiral 2,5-Disubstituted Pyrrolidines

5. Catalyzed Addition of Aldehydes to Activated Double Bonds?A New Synthetic Approach

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