Density-based quantification of steric effects: validation by Taft steric parameters from acid-catalyzed hydrolysis of esters-Reference-Cited by-同舟云学术

Density-based quantification of steric effects: validation by Taft steric parameters from acid-catalyzed hydrolysis of esters

Published:2024 Issue:35 Volume:26 Page:23447-23456
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Zhang Jingwen¹,He Xin²,Wang Bin³,Rong Chunying¹^ORCID,Zhao Dongbo⁴^ORCID,Liu Shubin⁵⁶^ORCID

Affiliation:

1. College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha, Hunan 410081, China

2. Institute of Frontier Chemistry, School of Chemistry and Chemical Engineering, Shandong University, Qingdao, Shandong 266237, China

3. Research Group of General Chemistry (ALGC), Vrije Universiteit Brussel (VUB), Pleinlaan 2, 1050 Brussels, Belgium

4. Institute of Biomedical Research, Yunnan University, Kunming 650500, Yunnan, China

5. Research Computing Center, University of North Carolina, Chapel Hill NC 27599-3420, USA

6. Department of Chemistry, University of North Carolina, Chapel Hill NC 27599-3290, USA

Abstract

Comparison of experimental scales and theoretical quantification of steric effects from acid-catalyzed ester hydrolysis was performed with remarkable agreement obtained.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CP/D4CP02702G

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