Clean synthesis of primary to tertiary carboxamides by CsOH-catalyzed aminolysis of nitriles in water-Reference-Cited by-同舟云学术

Clean synthesis of primary to tertiary carboxamides by CsOH-catalyzed aminolysis of nitriles in water

Published:2016 Issue:18 Volume:18 Page:4865-4870
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Li Yang¹²³⁴,Chen Haonan¹²³⁴,Liu Jianping¹²³⁴,Wan Xujun¹²³⁴,Xu Qing¹²³⁴⁵

Affiliation:

1. College of Chemistry and Materials Engineering

2. Wenzhou University

3. Wenzhou

4. P. R. China

5. School of Chemistry and Chemical Engineering

Abstract

Using CsOH as the only catalyst and utilizing its “cesium effect”, a clean synthesis of a wide range of primary, secondary, and tertiary carboxamides was achieved by aminolysis reactions of nitriles with ammonia, primary, or secondary amines in water.

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/GC/C6GC01565D

Reference73 articles.

1. The Chemistry of Amides, ed. J. Zabicky, Wiley-Interscience, New York, 1970

2. The Amide Linkage: Structural Significance in Chemistry, Biochemistry and Materials Science, ed. A. Greenberg, C. M. Breneman and J. F. Liebman, John Wiley & Sons, New York, 2000

3. I. Johansson , in Kirk-Othmer Encyclopedia of Chemical Technology, John Wiley & Sons, New York, 2004, vol. 2, pp. 442–463

4. Key green chemistry research areas—a perspective from pharmaceutical manufacturers

5. Polyesters and Polyamides, ed. B. L. Deopura, B. Gupta, M. Joshi and R. Alagirusami, CRC Press, Boca Raton, 2008

Cited by 49 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Iridium-Catalyzed asymmetric reduction of α,β-Unsaturated nitriles with water;Green Synthesis and Catalysis;2023-07

2. Condition-Controlled O-Acylation and N–O Bond Reduction of Hydroximic Acids with Thioacetic Acid;Organic Letters;2023-04-23

3. Advances in the Application of Acetonitrile in Organic Synthesis since 2018;Catalysts;2023-04-16

4. Direct Benzylic C–H Functionalization with Fluorenones under Visible-Light Irradiation;The Journal of Organic Chemistry;2023-02-01

5. PhI(OAc)₂-mediated C–N bond cleavage of acylhydrazines with amines for the synthesis of amides;New Journal of Chemistry;2023