Stable, yet “naked”, azo radical anion ArNNAr− and dianion ArNNAr2− (Ar = 4-CN-2,6-iPr2-C6H2) with selective CO2 activation-Reference-Cited by-同舟云学术

Stable, yet “naked”, azo radical anion ArNNAr− and dianion ArNNAr2− (Ar = 4-CN-2,6-iPr2-C6H2) with selective CO2 activation

Published:2020 Issue:22 Volume:56 Page:3285-3288
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Wang Wenqing¹²³⁴⁵,Tan Gengwen⁶⁷⁸⁹¹⁰,Feng Rui⁶⁷⁸⁹¹⁰,Fang Yong⁶⁷⁸⁹¹⁰,Chen Chao⁶⁷⁸⁹¹⁰,Ruan Huapeng⁶⁷⁸⁹¹⁰,Zhao Yue⁶⁷⁸⁹¹⁰^ORCID,Wang Xinping⁶⁷⁸⁹¹⁰^ORCID

Affiliation:

1. College of Chemistry and Material Science

2. Key Laboratory of Functional Molecular Solids

3. Ministry of Education

4. Anhui Laboratory of Molecule-Based Materials

5. Anhui Normal University

6. State Key Laboratory of Coordination Chemistry

7. School of Chemistry and Chemical Engineering

8. Nanjing University

9. Nanjing 210023

10. China

Abstract

The azo radical anion and dianion were isolated and structurally characterized. Their uncoordinated nature enables them to activate CO₂.

Funder

China Postdoctoral Science Foundation

National Basic Research Program of China

National Natural Science Foundation of China

Natural Science Foundation of Anhui Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/C9CC07382E

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