Cluster–π electronic interaction in a superatomic Au13 cluster bearing σ-bonded acetylide ligands-Reference-Cited by-同舟云学术

Cluster–π electronic interaction in a superatomic Au13 cluster bearing σ-bonded acetylide ligands

Published:2015 Issue:70 Volume:51 Page:13519-13522
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Sugiuchi Mizuho¹²³⁴,Shichibu Yukatsu¹²³⁴⁵,Nakanishi Takayuki⁶²⁷⁴,Hasegawa Yasuchika⁶²⁷⁴,Konishi Katsuaki¹²³⁴⁵

Affiliation:

1. Graduate School of Environmental Science

2. Hokkaido University

3. Sapporo 060-0810

4. Japan

5. Faculty of Environmental Earth Science

6. Faculty of Engineering

7. Sapporo 060-8628

Abstract

Electronic coupling between a Au₁₃ superatom and CC π-units was experimentally evidenced by the absorption spectrum. The existence of such a cluster–π electronic interaction was supported by theoretical calculations.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CC/C5CC04312C

Reference30 articles.

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