Five-coordinate MII-semiquinonate (M = Fe, Mn, Co) complexes: reactivity models of the catechol dioxygenases-Reference-Cited by-同舟云学术

Five-coordinate MII-semiquinonate (M = Fe, Mn, Co) complexes: reactivity models of the catechol dioxygenases

Published:2014 Issue:44 Volume:50 Page:5871-5873
ISSN:1359-7345
Container-title:Chem. Commun.
language:en
Short-container-title:Chem. Commun.

Author:

Wang Peng¹²³,Yap Glenn P. A.¹²³,Riordan Charles G.¹²³

Affiliation:

1. Department of Chemistry & Biochemistry

2. University of Delaware

3. Newark, USA

Abstract

The first mononuclear iron(ii)-semiquinonate has been prepared. Analogous manganese and cobalt adducts are reported, including a cobalt(ii)-semiquinonate that exhibits O₂-mediated intradiol oxidation.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CC/C3CC49143A

Reference33 articles.

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4. A highly reactive functional model for the catechol dioxygenases. Structure and properties of [Fe(TPA)DBC]BPh4

5. Structures and electronic properties of the catecholatoiron complexes in relation to catechol dioxygenases: chlorocatecholatoiron complexes are compared to the 3,5-di-tert-butylcatecholatoiron complex in the solid state and in solution

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