Modulation of in:out and out:out conformations in [X.X′.X′′] phosphatranes by Lewis acids

Author:

Sánchez-Sanz Goar12345ORCID,Trujillo Cristina67839ORCID,Alkorta Ibon10111213ORCID,Elguero José10111213ORCID

Affiliation:

1. Irish Centre of High-End Computing

2. Grand Canal Quay

3. Dublin 2

4. Ireland & School of Chemistry

5. University College Dublin

6. School of Chemistry

7. Trinity Biomedical Sciences Institute

8. Trinity College Dublin

9. Ireland

10. Instituto de Química Médica

11. CSIC

12. E–28006 Madrid

13. Spain

Abstract

It has been found that P⋯P lone pair-hole intramolecular interactions in phosphatranes are enhanced by the presence of Lewis acid. Interestingly, in:out structures are favored with respect to the out:out ones. This finding opens a chemical way to modulate structural changes and the equilibrium between both structures.

Funder

Ministerio de Economía y Competitividad

Universidad Autónoma de Madrid

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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