Regio- and stereoselective divergent cross-coupling of alkynes and disubstituted alkenes <i>via</i> photoredox cobalt dual catalysis-Reference-Cited by-同舟云学术

Regio- and stereoselective divergent cross-coupling of alkynes and disubstituted alkenes via photoredox cobalt dual catalysis

Published:2023 Issue:24 Volume:10 Page:6070-6080
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Zhang Shi-Qi¹²,Li Yan-Lin¹,Cui Kun¹,Chen Chen¹²,Gu Zheng-Yang³^ORCID,He Hu⁴,Xia Ji-Bao¹⁵^ORCID

Affiliation:

1. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics (LICP), University of Chinese Academy of Sciences, Chinese Academy of Sciences, Lanzhou 730000, China

2. University of Chinese Academy of Sciences, Beijing, 100049, China

3. College of Textiles and Clothing, Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province, Yancheng Institute of Technology, Jiangsu, China

4. Hangzhou SynRx Therapeutics Biomedical Technology Co., Hangzhou, 311121, China

5. College of Material Chemistry and Chemical Engineering, Key Laboratory of Organosilicon Chemistry and Material Technology, Ministry of Education, Hangzhou Normal University, Hangzhou 311121, Zhejiang, China

Abstract

Regio- and stereoselective divergent cross-coupling of alkynes and gem-disubstituted alkenes has been reported by merging visible light photoredox and cobalt catalysis. The selective ene-type or reductive coupling reaction has been achieved by stwich of different ligands.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Jiangsu Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QO/D3QO01281F

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