31P nuclear spin singlet lifetimes in a system with switchable magnetic inequivalence: experiment and simulation-Reference-Cited by-同舟云学术

31P nuclear spin singlet lifetimes in a system with switchable magnetic inequivalence: experiment and simulation

Published:2021 Issue:35 Volume:23 Page:19465-19471
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Korenchan David E.¹^ORCID,Lu Jiaqi¹^ORCID,Levitt Malcolm H.²^ORCID,Jerschow Alexej¹^ORCID

Affiliation:

1. Department of Chemistry, New York University, New York, NY, USA

2. School of Chemistry, University of Southampton, Southampton, UK

Abstract

31P NMR nuclear spin singlet order is reported for the first time. Experiments and molecular dynamics simulations indicate that the singlet order relaxes primarily via chemical shift anisotropy at high magnetic field strengths.

Funder

University of Southampton

National Science Foundation

Heising-Simons Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D1CP03085J

Reference39 articles.

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3. M. H.Levitt , Encyclopedia of Magnetic Resonance , 2010

4. Singlet Nuclear Magnetic Resonance

5. Symmetry versus entropy: Long-lived states and coherences

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