The bimetallic effect promotes the activity of Rh in catalyzed selective hydrogenation of phenol-Reference-Cited by-同舟云学术

The bimetallic effect promotes the activity of Rh in catalyzed selective hydrogenation of phenol

Published:2022 Issue:74 Volume:58 Page:10357-10360
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Li Shiwei¹²,Zhao Huachao¹²,Ran Wei¹,Liu Jingfu¹²³^ORCID,Liu Rui¹²³^ORCID

Affiliation:

1. State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing, 100085, China

2. College of Resources and Environment, University of Chinese Academy of Sciences, Beijing, 100049, China

3. School of Environment, Hangzhou Institute of Advanced Study, UCAS, Hangzhou, 310024, China

Abstract

Bimetallic Au@Rh catalysts with modulated electronic states by the underlying Au core showed satisfactory performance in the selective hydrogenation of phenols toward cyclohexanones compared with monometallic Rh nanoparticle catalysts.

Funder

National Natural Science Foundation of China

Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences

Youth Innovation Promotion Association of the Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC03571E

Reference15 articles.

1. Bimetallic monolayer catalyst breaks the activity–selectivity trade-off on metal particle size for efficient chemoselective hydrogenations

2. Rhodium–nickel bimetallic nanocatalysts: high performance of room-temperature hydrogenation

3. Selective hydrogenation of phenol to cyclohexanone by SiO2-supported rhodium nanoparticles under mild conditions

4. Two-dimensional N-doped Pd/carbon for highly efficient heterogeneous catalysis

5. Highly efficient hydrogenation of phenol to cyclohexanol over Ni-based catalysts derived from Ni-MOF-74

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