Formation of cobalt–oxygen intermediates by dioxygen activation at a mononuclear nonheme cobalt(ii) center-Reference-Cited by-同舟云学术

Formation of cobalt–oxygen intermediates by dioxygen activation at a mononuclear nonheme cobalt(ii) center

Published:2021 Issue:34 Volume:50 Page:11889-11898
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Malik Deesha D.¹^ORCID,Chandra Anirban²,Seo Mi Sook¹^ORCID,Lee Yong-Min¹^ORCID,Farquhar Erik R.³^ORCID,Mebs Stefan⁴,Dau Holger⁴^ORCID,Ray Kallol²^ORCID,Nam Wonwoo¹^ORCID

Affiliation:

1. Department of Chemistry and Nano Science, Ewha Womans University, Seoul 03760, Korea

2. Department of Chemistry, Humboldt-Universität zu Berlin, Brook-Taylor-Straße 2, 12489 Berlin, Germany

3. Case Center for Synchrotron Biosciences, NSLS-II, Brookhaven National Laboratory Upton, NY 11973, USA

4. Freie Universität Berlin, FB Physik, Arnimallee 14, 14195 Berlin, Germany

Abstract

The present study represents the first example showing the generation of Co(ii)-alkylperoxide and Co(iv)-oxo intermediates by employing dioxygen as an oxidant.

Funder

Deutsche Forschungsgemeinschaft

National Research Foundation of Korea

U.S. Department of Energy

Foundation for the National Institutes of Health

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT01996A

Reference86 articles.