An electrically conducting molecular crystal composed of a magnetic iron(iii) complex (S = 1/2) with a large aromatic ligand, 1,2-naphthlalocyanine (C4h isomer): towards the development of molecular spintronics-Reference-Cited by-同舟云学术

An electrically conducting molecular crystal composed of a magnetic iron(iii) complex (S = 1/2) with a large aromatic ligand, 1,2-naphthlalocyanine (C4h isomer): towards the development of molecular spintronics

Published:2021 Issue:17 Volume:50 Page:5789-5794
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Yamaguchi Masayuki¹²³⁴,Iwamura Sayaka¹²³⁴,Mine Kosuke¹²³⁴,Murakawa Hiroshi⁵⁶⁷⁴,Hanasaki Noriaki⁵⁶⁷⁴,Matsuda Masaki¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Kumamoto University

3. Kumamoto 860-8555

4. Japan

5. Department of Physics

6. Osaka University

7. Osaka 560-0043

Abstract

An electrically conducting molecular crystal, Ph₄P[Fe^III(1,2-Nc)(CN)₂]₂ (Ph₄P = tetraphenylphosphonium and 1,2-Nc = C_4h isomer of 1,2-naphthalocyanine), was fabricated as a new coordination compound with a strong π–d interaction.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT00588J

Reference19 articles.

1. Spintronics: Fundamentals and applications

2. Spintronics: A Spin-Based Electronics Vision for the Future

3. Molecular spintronics: the role of coordination chemistry

4. Magnetic-field-induced superconductivity in a two-dimensional organic conductor

5. Phase diagram and anomalous constant resistivity state of a magnetic organic superconducting alloy, λ-(BETS)2FexGa1−xCl4

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