Heterogeneous parahydrogen induced polarization on Rh-containing silicalite-1 zeolites: effect of the catalyst structure on signal enhancement

Author:

Wang Weiyu12ORCID,Sun Qiming3ORCID,Wang Qiang12,Li Shenhui12ORCID,Xu Jun12ORCID,Deng Feng12ORCID

Affiliation:

1. National Centre for Magnetic Resonance in Wuhan, State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics and Mathematics, Innovation Academy for Precision Measurement Science and Technology, Chinese Academy of Sciences, Wuhan 430071, China

2. University of Chinese Academy of Sciences, Beijing 100049, China

3. Innovation Center for Chemical Sciences, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China

Abstract

Parahydrogen-induced polarization (PHIP) on Rh-containing silicalite-1 catalysts is studied using both liquid-state and in situ magic angle spinning NMR techniques and the catalyst structure effect is revealed.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Hubei Province

Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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