Disarming the alkoxide trap to access a practical FeCl<sub>3</sub> system for borrowing-hydrogen <i>N</i>-alkylation-Reference-Cited by-同舟云学术

Disarming the alkoxide trap to access a practical FeCl₃ system for borrowing-hydrogen N-alkylation

Published:2022 Issue:18 Volume:9 Page:4803-4817
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Ye Zongren¹,Yang Zhenjie¹,Yang Chenhui¹,Huang Ming¹²^ORCID,Xu Xianfang¹,Ke Zhuofeng¹³^ORCID

Affiliation:

1. School of Materials Science & Engineering, School of Chemistry, PCFM Lab, Sun Yat-sen University, Guangzhou 510006, P. R. China

2. School of Clinical Pharmacy, Guangdong Pharmaceutical University, Guangzhou 510006, P. R. China

3. Guangdong Provincial Key Laboratory of Optical Chemicals, XinHuaYue Group, Maoming, 525000, P.R. China

Abstract

Disarming the alkoxide trap using an in situ reduction strategy to access a practical FeCl3 and N-heterocyclic carbene system for borrowing-hydrogen N-alkylation.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QO/D2QO00825D

Reference76 articles.

1. The Atom Economy—A Search for Synthetic Efficiency

2. Hydrogen Autotransfer in the N-Alkylation of Amines and Related Compounds using Alcohols and Amines as Electrophiles

3. The Give and Take of Alcohol Activation

4. Applications of Acceptorless Dehydrogenation and Related Transformations in Chemical Synthesis

5. Substitution of alcohols by N-nucleophiles via transition metal-catalyzed dehydrogenation

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