Electronic structure regulation of halogen anion-intercalated MgAl-LDH for highly selective photothermal oxidation of CH<sub>4</sub>-Reference-Cited by-同舟云学术

Electronic structure regulation of halogen anion-intercalated MgAl-LDH for highly selective photothermal oxidation of CH₄

Published:2023 Issue:6 Volume:10 Page:1769-1774
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Sun Xiaoliang¹,Xu Yanqi¹²,Bai Sha¹,Liu Guihao¹,Shen Tianyang¹,Song Yu-Fei¹^ORCID

Affiliation:

1. State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, P. R. China

2. Key Laboratory of New Processing Technology for Nonferrous Metal & Materials, Ministry of Education, Collaborative Innovation Center for Exploration of Nonferrous Metal Deposits and Efficient Utilization of Resources, Guilin University of Technology, Guilin 541004, China

Abstract

The photothermal catalytic oxidation of CH4 was performed on a series of halogen anion-intercalated MgAl-LDHs. MgAl-F exhibited 86.5% selectivity for CO and completely inhibited the production of CO2, arising from the strong interaction of F− with OH on the host layer.

Funder

Fundamental Research Funds for the Central Universities

Beijing Synchrotron Radiation Facility

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QI/D2QI02772K

Reference30 articles.

1. Photocatalytic conversion of methane