Electron and energy transfer in a porphyrin–oxoporphyrinogen–fullerene triad, ZnP–OxP–C60

Author:

Chahal Mandeep K.1234ORCID,Gobeze Habtom B.5678,Webre Whitney A.5678,Karr Paul A.910118,Payne Daniel T.12234ORCID,Ariga Katsuhiko123413ORCID,D’Souza Francis5678ORCID,Hill Jonathan P.1234ORCID

Affiliation:

1. International Center for Materials Nanoarchitectonics (MANA)

2. National Institute for Materials Science (NIMS)

3. Tsukuba

4. Japan

5. Department of Chemistry

6. University of North Texas

7. Denton

8. USA

9. Department of Physical Sciences and Mathematics

10. Wayne State College

11. Wayne

12. International Center for Young Scientists (ICYS)

13. Department of Advanced Materials Science

Abstract

Competitive energy and electron transfer in a newly synthesized supramolecular triad composed of zinc porphyrin, oxoporphyrinogen and C60 has been demonstrated using ultrafast pump–probe spectroscopy.

Funder

National Institute for Materials Science

National Science Foundation

Japan Society for the Promotion of Science

Core Research for Evolutional Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference50 articles.

1. L. R. Milgrom , The Colors of Life , Oxford University Press , 1997

2. J. P. Hill , F.D’Souza and K.Ariga , Porphyrinoids: Highly Colored, Redox Active Scaffolds for Supramolecular Synthesis , in Supramolecular Chemistry: From Molecules to Nanomaterials , ed. P. A. Gale and J. W. Steed , John Wiley & Sons Ltd , Chichester, UK , 2012 , pp. 1713–1730

3. The Porphyrin Handbook , ed. K. M. Kadish , K. M. Smith and R. Guilard , Academic Press , Burlington, MA , 2000

4. STRUCTURE AND FUNCTION OF PHOTOSYSTEMS I AND II

5. Mechanism of light induced water splitting in Photosystem II of oxygen evolving photosynthetic organisms

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