Synthesis, structure and aromaticity of carborane-fused carbo- and heterocycles
Author:
Affiliation:
1. Department of Chemistry and State Key Laboratory of Synthetic Chemistry
2. The Chinese University of Hong Kong
3. China
Abstract
The results of molecular structures, NMR data, and NICS (nucleus-independent chemical shift) and ISE (isomerization stabilization energy) values as well as molecular orbital analyses clearly suggest the presence of considerable aromatic character in the exo five-membered ring of carborane-fused carbo- and heterocycles and considerable conjugation between a 3-D carborane and a fused 2-D π-ring system.
Funder
Research Grants Council, University Grants Committee
NSFC
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/SC/C7SC04722C
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