Metal-catalyzed formation of 1,3-cyclohexadienes: a catalyst-dependent reaction-Reference-Cited by-同舟云学术

Metal-catalyzed formation of 1,3-cyclohexadienes: a catalyst-dependent reaction

Published:2015 Issue:4 Volume:13 Page:1225-1233
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Zhu Shifa¹²³⁴,Huang Xiaobing¹²³⁴,Zhao Tian-Qi⁵⁶⁷⁸,Ma Tongmei¹²³⁴,Jiang Huanfeng¹²³⁴

Affiliation:

1. School of Chemistry and Chemical Engineering

2. South China University of Technology

3. Guangzhou City

4. China

5. Department of Chemistry

6. The University of Hong Kong

7. Pokfulam

8. Hong Kong

Abstract

A metal-dependent and complementary catalytic method to synthesize the cyclohexadienes has been developed. When gold or indium salts were used as catalysts, 1,3-cyclohexadiene (1,3-CHD) could be obtained; when Cu(OTf)₂ was used as the catalyst, however, another isomer 2,4-cyclohexadiene (2,4-CHD) was furnished instead.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/OB/C4OB01922A

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