Insight into catalyst speciation and hydrogen co-evolution during enantioselective formic acid-driven transfer hydrogenation with bifunctional ruthenium complexes from multi-technique operando reaction monitoring-Reference-Cited by-同舟云学术

Insight into catalyst speciation and hydrogen co-evolution during enantioselective formic acid-driven transfer hydrogenation with bifunctional ruthenium complexes from multi-technique operando reaction monitoring

Published:2019 Issue: Volume:220 Page:45-57
ISSN:1359-6640
Container-title:Faraday Discussions
language:en
Short-container-title:Faraday Discuss.

Author:

Berry Daniel B. G.¹²³⁴^ORCID,Codina Anna⁵⁶⁴,Clegg Ian⁵⁶⁴,Lyall Catherine L.¹²³⁴⁷^ORCID,Lowe John P.¹²³⁴⁷^ORCID,Hintermair Ulrich¹²³⁴⁷^ORCID

Affiliation:

1. Department of Chemistry

2. University of Bath

3. BA2 7AY Bath

4. UK

5. Bruker UK Ltd

6. CV4 9GH Coventry

7. Dynamic Reaction Monitoring Facility

Abstract

Operando spectroscopy shows a transition from dehydrogenation to hydrogen transfer during the reaction, and allows measuring optimal conditions for maximum rate and efficiency.

Funder

Royal Society

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/FD/C9FD00060G

Reference32 articles.

1. Nat. Catal. , 2018 , 1 , 165166 , https://www.nature.com/articles/s41929-018-0050-4

2. Practical aspects of real-time reaction monitoring using multi-nuclear high resolution FlowNMR spectroscopy