Mechanisms of methyl formate production during electron-induced processing of methanol–carbon monoxide ices-Reference-Cited by-同舟云学术

Mechanisms of methyl formate production during electron-induced processing of methanol–carbon monoxide ices

Published:2021 Issue:20 Volume:23 Page:11649-11662
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Schmidt Fabian¹²³⁴⁵^ORCID,Swiderek Petra¹²³⁴⁵^ORCID,Scheele Tarek¹²³⁴⁵^ORCID,Bredehöft Jan H.¹²³⁴⁵^ORCID

Affiliation:

1. Universität Bremen

2. Fachbereich 2 (Chemie/Biologie)

3. Institut für Angewandte und Physikalische Chemie

4. Leobener Straße 5

5. D-28359 Bremen

Abstract

A novel mechanism is proposed for the electron-induced production of methyl formate from CO and CH₃OH which is relevant for interstellar ice chemistry. A key-step in this reaction is the formation of an intermediate CH₃OCO radical.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D1CP01255J

Reference53 articles.

1. Photochemistry and Astrochemistry: Photochemical Pathways to Interstellar Complex Organic Molecules

2. Formation rates of complex organics in UV irradiated CH3OH-rich ices

3. Low-energy electron-induced chemistry of condensed methanol: implications for the interstellar synthesis of prebiotic molecules

4. Electron-Induced Processing of Methanol Ice

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1. Astro-electrochemistry of NH3 clusters and ice: e− trapping, stability, and electron transfer;Monthly Notices of the Royal Astronomical Society;2024-05-06

2. Electron Scattering from Methyl Formate (HCOOCH₃): A Joint Theoretical and Experimental Study;The Journal of Physical Chemistry A;2023-08-29

3. Mechanisms of Electron-Induced Chemistry in Molecular Ices;Atoms;2022-02-21

4. Molecular synthesis in ices triggered by dissociative electron attachment to carbon monoxide;The European Physical Journal D;2021-12