Affiliation:
1. Department of Chemistry and Biochemistry, University of Windsor, 401 Sunset Avenue, ON, N9B 3P4, Canada
Abstract
Herein, we report the first example of a ‘tucked-in’ iron diphosphine complex, formed through deprotonation of a Cp*–(CH̲3) (Cp* = C5Me5−) group by n-butyllithium.
Funder
Natural Sciences and Engineering Research Council of Canada
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis
Reference40 articles.
1. A New Type of Organo-Iron Compound
2. Robert H.Crabtree , The Organometallic Chemistry of the Transition Metals , John Wiley & Sons, Inc. , Hoboken, NJ ., 6th edn, 2014
3. J.Hartwig , Organotransition Metal Chemistry: From Bonding to Catalysis , University Science Books , Mill Valley, CA ., 2010
4. C.Elschenbroich , Organometallics , Wiley-VCH , Weinheim, Germany , 3rd edn, 2006
5. Pentamethylcyclopentadienyl metal complexes: an entry to metal carbonyl derivatives with metal- metal multiple bonding