Twisted [C2O5]2−-groups in Ba[C2O5] pyrocarbonate-Reference-Cited by-同舟云学术

Twisted [C₂O₅]²⁻-groups in Ba[C₂O₅] pyrocarbonate

Published:2023 Issue:80 Volume:59 Page:11951-11954
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Spahr Dominik¹^ORCID,Bayarjargal Lkhamsuren¹,Haussühl Eiken¹,Luchitskaia Rita¹,Friedrich Alexandra²^ORCID,Milman Victor³^ORCID,Fedotenko Timofey⁴,Winkler Björn¹

Affiliation:

1. Goethe University Frankfurt, Institute of Geosciences, Altenhöferallee 1, Frankfurt 60438, Germany

2. University of Würzburg, Institute of Inorganic Chemistry, Am Hubland, Würzburg 97074, Germany

3. Dassault Systèmes BIOVIA, 334 Cambridge Science Park, Cambridge CB4 0WN, UK

4. DESY, Notkestrasse 85, Hamburg 22607, Germany

Abstract

Ba[C2O5] was synthesized by reacting Ba[CO3] with CO2 and contains twisted [C2O5]2−-groups, an atomic arrangement previously not observed in carbonates.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D3CC03324D

Reference28 articles.

1. Sr[C₂O₅] is an Inorganic Pyrocarbonate Salt with [C₂O₅]^2– Complex Anions

2. Synthesis and Structure of Pb[C₂O₅]: An Inorganic Pyrocarbonate Salt

3. Aplanarity of CO3 groups: a theoretical investigation

4. Carbonates: Mineralogy and Chemistry , ed. R. J. Reeder , De Gruyter , Berlin, Boston , 1983

5. Solubility and Solvation of Carbon Dioxide in the Molten Li2CO3/Na2CO3/K2CO3 (43.5:31.5:25.0 mol-%) Eutectic Mixture at 973 K I. Experimental Part

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