Highly chemoselective homologative assembly of the α-substituted methylsulfinamide motif from <i>N</i>-sulfinylamines-Reference-Cited by-同舟云学术

Highly chemoselective homologative assembly of the α-substituted methylsulfinamide motif from N-sulfinylamines

Published:2023 Issue:74 Volume:59 Page:11065-11068
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Malik Monika¹,Senatore Raffaele¹,Castiglione Davide²,Roller-Prado Alexander³,Pace Vittorio¹²^ORCID

Affiliation:

1. Department of Pharmaceutical Sciences, Division of Pharmaceutical Chemistry, University of Vienna, Josef-Holaubek-Platz 2, 1090, Vienna, Austria

2. Department of Chemistry, Via Giuria 7, University of Turin, Turin 10125, Italy

3. Department of Inorganic Chemistry – Functional Materials, University of Vienna, Waehringerstrasse 42, 1090, Vienna, Austria

Abstract

α-Substituted methylsulfinamide are prepared through the homologation of electrophilic N-sulfinylamines with Li-CHXY reagents.

Funder

Dipartimenti di Eccellenza

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D3CC03326K

Reference67 articles.

1. Natural Products Containing a Nitrogen–Sulfur Bond

2. Asymmetric Synthesis of S(IV) and S(VI) Stereogenic Centers

3. Modern Stereoselective Synthesis of Chiral Sulfinyl Compounds

4. Synthesis and Applications of tert-Butanesulfinamide

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