Ruthenium and palladium bimetallic nanoparticles achieving functional parity with a rhodium cocatalyst for TiO<sub>2</sub>-photocatalyzed ring hydrogenation of benzoic acid-Reference-Cited by-同舟云学术

Ruthenium and palladium bimetallic nanoparticles achieving functional parity with a rhodium cocatalyst for TiO₂-photocatalyzed ring hydrogenation of benzoic acid

Published:2023 Issue:33 Volume:25 Page:21868-21874
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Nakanishi Kousuke¹,Araki Sakae¹,Nomoto Kousuke¹,Onoue Yuichi¹,Yagi Ryosuke¹,Asakura Hiroyuki²,Tanaka Atsuhiro²,Tanaka Tsunehiro³^ORCID,Kominami Hiroshi²^ORCID

Affiliation:

1. Department of Molecular and Material Engineering, Graduate School of Science and Engineering, Kindai University, Kowakae, Higashiosaka, Osaka 577-8502, Japan

2. Department of Applied Chemistry, Faculty of Science and Engineering, Kindai University, Kowakae, Higashiosaka, Osaka 577-8502, Japan

3. Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Kyotodaigaku Katsura, Nishikyo-ku, Kyoto 615-8510, Japan

Abstract

Cyclohexanecarboxylic acid as the ring hydrogenation product of benzoic acid was successfully obtained when Ru and Pd were simultaneously loaded on TiO2, indicating that this bimetallic system can be used in place of an Rh cocatalyst.

Funder

Kindai University

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CP/D3CP01379K

Reference30 articles.

1. Biosynthetic studies on ansatrienin A. Formation of the cyclohexanecarboxylic acid moiety

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3. Rhodium Nanoparticle Encapsulated in a Porous Carbon Shell as an Active Heterogeneous Catalyst for Aromatic Hydrogenation

4. Solid state synthesis of Ru–MC with highly dispersed semi-embedded ruthenium nanoparticles in a porous carbon framework for benzoic acid hydrogenation

5. Significant effect of base on the improvement of selectivity in the hydrogenation of benzoic acid over NiZrB amorphous alloy supported on γ-Al2O3

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