Reactions of a BICAAC with hydroboranes: propensity for Lewis adduct formation and carbene insertion into the B–H bond
Author:
Affiliation:
1. Department of Chemical Sciences
2. Indian Institute of Science Education and Research Mohali
3. Mohali 140306
4. India
Abstract
A BICAAC interacts differently with different boranes: Lewis adducts were formed with simple hydroboranes and insertion of the carbene carbon into the B–H bond was observed with more hydridic boranes.
Funder
Science and Engineering Research Board
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT03382C
Reference58 articles.
1. S. P. Nolan , N-Heterocyclic Carbenes in Synthesis , Wiley-VCH , Weinheim , 2006
2. Synthesis and Reactions of N-Heterocyclic Carbene Boranes
3. NHCs in Main Group Chemistry
4. Cyclic (Alkyl)(Amino)Carbenes (CAACs): Stable Carbenes on the Rise
5. Cyclic Alkyl(amino) Carbene Stabilized Complexes with Low Coordinate Metals of Enduring Nature
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