Inconsistency between superstructure stability and long-term cyclability of oxygen redox in Na layered oxides

Author:

Liu Hui1,Zhao Chong1,Wu Xiang1,Hu Chunjing1,Geng Fushan1,Shen Ming1ORCID,Hu Bei2,Hu Bingwen1,Li Chao1ORCID

Affiliation:

1. Shanghai Key Laboratory of Magnetic Resonance, School of Physics and Electronic Science, East China Normal University, Shanghai 200241, P. R. China

2. National Key Laboratory of Science and Technology on Micro/Nano Fabrication, Key Laboratory for Thin Film and Microfabrication of the Ministry of Education, Department of Micro/Nano Electronics, School of Electronic Information and Electrical Engineering, Shanghai Jiao Tong University, Shanghai 200240, P. R. China

Abstract

The preservation of LiTM (i.e., Na–O–Li configurations) determines the cyclability of oxygen redox rather than the stability of the superstructure.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

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