Configurational landscape of chiral iron(ii) bis(phosphane) complexes

Author:

Estevan Francisco1234ORCID,Feliz Marta5674ORCID

Affiliation:

1. Departament de Química Inorgànica

2. Universitat de València

3. 46100 Burjassot-Valencia

4. Spain

5. Instituto de Tecnología Química

6. Universitat Politècnica de València-Consejo Superior de Investigaciones Científicas

7. 46022 Valencia

Abstract

An [FeH(η2-H2){Me-DuPhos}2]+ complex reacts with ethers and halides to give cis- and trans-dihydrogen substituted isomers and [FeX{Me-DuPhos}2]+ (X = Cl, I) complexes.

Funder

Ministerio de Ciencia e Innovación

Consejo Superior de Investigaciones Científicas

Universitat de València

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference82 articles.

1. Hydrogen and Dihydrogen Bonds in the Reactions of Metal Hydrides

2. Dihydrogen Complexes as Homogeneous Reduction Catalysts

3. Metal-Hydrogen Bond Cleavage Reactions of Transition Metal Hydrides: Hydrogen Atom, Hydride, and Proton Transfer Reactions

4. R. H. Morris , in Encyclopedia of Inorganic and Bioinorganic Chemistry , ed. R. H. Crabtree , 2018 , pp. 1–12

5. Catalysis without Precious Metals , ed. R. M. Bullock , Wiley-VCH , Weinheim , 2010

Cited by 1 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Chiral-at-iron compounds with phosphanes;Coordination Chemistry Reviews;2024-03

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