A sequential cyclization/π-extension strategy for modular construction of nanographenes enabled by stannole cycloadditions

Author:

Bergman Harrison M.1ORCID,Beattie D. Dawson1,Kiel Gavin R.1ORCID,Handford Rex C.1,Liu Yi2ORCID,Tilley T. Don1ORCID

Affiliation:

1. Department of Chemistry, University of California, Berkeley, California 94720, USA

2. Molecular Foundry, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA

Abstract

Stannoles are introduced as a new, spontaneously aromatizing diene for [4 + 2] cycloadditions that can be easily introduced into diverse conjugated systems, facilitating the efficient synthesis of complex PAHs and their π-extension.

Funder

Division of Chemistry

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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