CO2 conversion to phenyl isocyanates by uranium(vi) bis(imido) complexes-Reference-Cited by-同舟云学术

CO2 conversion to phenyl isocyanates by uranium(vi) bis(imido) complexes

Published:2020 Issue:3 Volume:56 Page:431-434
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Maria Leonor¹²³⁴⁵^ORCID,Bandeira Nuno A. G.⁶⁷³⁸⁵^ORCID,Marçalo Joaquim¹²³⁴⁵^ORCID,Santos Isabel C.¹²³⁴⁵^ORCID,Gibson John K.⁹¹⁰¹¹¹²^ORCID

Affiliation:

1. Centro de Ciências e Tecnologias Nucleares (C2TN)

2. Instituto Superior Técnico

3. Universidade de Lisboa

4. 2695-066 Bobadela

5. Portugal

6. BioISI and Centro de Química e Bioquiímica

7. Faculdade de Ciências

8. 1749-016 Lisboa

9. Chemical Sciences Division

10. Lawrence Berkeley National Laboratory

11. Berkeley

12. USA

Abstract

U(vi) trans-bis(imido) complexes [U(κ⁴{(^tBu2ArO)₂Me₂-cyclam})(NPh)(NPh^R)] react with CO₂ to afford U(vi) trans-[OUNR]²⁺ complexes with elimination of isocyanates. These are unprecedented examples of CO₂ cleavage mediated by U(vi) imido complexes.

Funder

Basic Energy Sciences

Fundação para a Ciência e a Tecnologia

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/C9CC07411B

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