Quantum chemical clarification of the alkyl chain length threshold of nonionic surfactants for monolayer formation at the air/water interface

Author:

Vysotsky Yu. B.123,Kartashynska E. S.123,Belyaeva E. A.4567,Vollhardt D.8910,Fainerman V. B.11123,Miller R.8910

Affiliation:

1. Donetsk National Technical University

2. 83000 Donetsk

3. Ukraine

4. Saint Petersburg State University

5. Institute of Chemistry

6. St. Petersburg

7. Russia

8. Max Planck Institute of Colloids and Interfaces

9. D-14424 Potsdam/Golm

10. Germany

11. Donetsk Medical University

12. Donetsk 83003

Abstract

A theoretical basis is introduced for the experimental fact that for various surfactant classes the alkyl chain length threshold varies for the formation of condensed monolayers.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference35 articles.

1. Handbook of aqueous solubility data, ed. S. H. Yalkowsky, Y. He and P. Jain, CRC Press, New York, 2010, p. 1622

2. A.-F. Mingotaud , C.Mingotaud and L. K.Patterson, Handbook of Monolayers, Academic Press, San Diego, 1993, vol. 1

3. Simplified method of the quantum chemical analysis for determination of thermodynamic parameters of 2D cluster formation of amphiphilic compounds at the air/water interface

4. Preparation of monolayers and stacked layers of 1-octadecanethiol

5. Quantum Chemical Analysis of Thermodynamics of 2D Cluster Formation of n-Thioalcohols at the Air/Water Interface

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