Intramolecular Lewis pairs with two acid sites – reactivity differences between P- and N-based systems-Reference-Cited by-同舟云学术

Intramolecular Lewis pairs with two acid sites – reactivity differences between P- and N-based systems

Published:2016 Issue:43 Volume:45 Page:17319-17328
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Körte Leif A.¹²³⁴⁵,Blomeyer Sebastian¹²³⁴⁵,Heidemeyer Shari¹²³⁴⁵,Nissen Jan Hendrick¹²³⁴⁵,Mix Andreas¹²³⁴⁵,Neumann Beate¹²³⁴⁵,Stammler Hans-Georg¹²³⁴⁵,Mitzel Norbert W.¹²³⁴⁵

Affiliation:

1. Anorganische Chemie und Strukturchemie

2. Centrum für molekulare Materialien CM2

3. Fakultät für Chemie

4. Universität Bielefeld

5. 33615 Bielefeld

Abstract

Unlike the aniline PhN[(CH₂)₃B(C₆F₅)₂]₂ the doubly hydroborated species (^tBu/Ph)P[(CH₂)₃B(C₆F₅)₂]₂ show no dynamic exchange of the boron Lewis acid functions in solution and are not catalytically active in terms of H/D-scrambling as well as hydrogenation reactions.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT03490J

Reference57 articles.

1. Frustrated Lewis pairs: a new strategy to small molecule activation and hydrogenation catalysis

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3. Frustrated Lewis Pair Chemistry: Development and Perspectives

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5. Facile Heterolytic Cleavage of Dihydrogen by Phosphines and Boranes

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