A non-symmetric sulfur-based O,C,O-chelating pincer ligand leading to chiral germylene and stannylene-Reference-Cited by-同舟云学术

A non-symmetric sulfur-based O,C,O-chelating pincer ligand leading to chiral germylene and stannylene

Published:2019 Issue:7 Volume:48 Page:2399-2406
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Deak Noemi¹²³⁴⁵^ORCID,Thillaye du Boullay Olivier⁶⁷⁸⁹¹⁰,Moraru Ionut-Tudor¹²³⁴⁵,Mallet-Ladeira Sonia¹¹¹²¹³⁷¹⁴,Madec David⁶⁷⁸⁹¹⁰^ORCID,Nemes Gabriela¹²³⁴⁵^ORCID

Affiliation:

1. Universitatea Babes-Bolyai

2. Facultatea de Chimie si Inginerie Chimica

3. Departamentul de Chimie

4. Cluj-Napoca

5. Romania

6. Université de Toulouse

7. UPS

8. LHFA (Laboratoire Hétérochimie Fondamentale et Appliquée), UMR/CNRS 5069

9. F-31062 Toulouse Cedex 09

10. France

11. Institut de Chimie de Toulouse

12. FR2599

13. Université Paul Sabatier

14. F-31062 Toulouse Cedex 9

Abstract

New chiral heteroleptic germanium(ii) and tin(ii) metallylenes were obtained using 1-(para-tolylsulfinyl)-3-tosyl-5-tert-butyl-benzene as a non-symmetric O,C,O-chelating pincer ligand.

Funder

Consiliul National al Cercetarii Stiintifice

Centre National de la Recherche Scientifique

Université de Toulouse

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C8DT05116J

Reference40 articles.

1. Organometallic Pincer Chemistry , ed. G. van Koten and D. Milstein , Springer Berlin Heidelberg , Berlin, Heidelberg , 2013 , vol. 40

2. The Chemistry of Pincer Compounds , ed. D. Morales-Morales and C. Jensen , Elsevier , 2007

3. G. van Koten and R. A.Gossage , The Privileged Pincer-Metal Platform: Coordination Chemistry & Applications , Springer International Publishing , Cham , 2016 , vol. 54

4. D. Morales-Morales , Pincer Compounds - Chemistry and Applications , Elsevier , 2018

5. Non-symmetric pincer ligands: complexes and applications in catalysis

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