Heteroanion induced structural asymmetricity centered on Ru sites switches the rate-determining step of acid water oxidation

Author:

Chen Ding1,Zhao Hongyu1,Yu Ruohan2,Yu Kesong1,Zhu Jiawei1,Jiao Jixiang1,Mu Xueqin1,Yu Jun1ORCID,Wu Jinsong2ORCID,Mu Shichun1ORCID

Affiliation:

1. State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China

2. NRC (Nanostructure Research Centre), Wuhan University of Technology, Wuhan 430070, China

Abstract

The intervening Se induces the structural asymmetricity of Ru-S6 octahedrons and then regulates the electronic structure of the active Ru site, which possesses excellent acid water oxidation performance as an Ir-free catalyst.

Funder

National Natural Science Foundation of China

State Key Laboratory of Advanced Technology for Materials Synthesis and Processing

Publisher

Royal Society of Chemistry (RSC)

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