Mechanistic investigation of 1,3-dipolar cycloaddition between bifunctional 2-pyridylselenyl reagents and nitriles including reactions with cyanamides-Reference-Cited by-同舟云学术

Mechanistic investigation of 1,3-dipolar cycloaddition between bifunctional 2-pyridylselenyl reagents and nitriles including reactions with cyanamides

Published:2023 Issue:25 Volume:25 Page:3691-3701
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Artemjev Alexey A.¹^ORCID,Kubasov Alexey S.²^ORCID,Kuznetsov Maxim L.³^ORCID,Grudova Mariya V.⁴,Khrustalev Victor N.¹⁴^ORCID,Kritchenkov Andreii S.¹,Tskhovrebov Alexander G.¹^ORCID

Affiliation:

1. Peoples' Friendship University of Russia, 6 Miklukho-Maklaya Street, Moscow, 117198, Russian Federation

2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninsky Prosp. 31, Moscow, Russian Federation

3. Centro de Química Estrutural, Institute of Molecular Sciences, Departamento de Engenharia Química, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001 Lisboa, Portugal

4. N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Prosp, Moscow, Russian Federation

Abstract

2-Pyridylselenyl reagents react with cyanamides to furnish pyridine-fused selenodiazolium salts. Theoretical calculations suggested that the coupling of 2-pyridylchalcogenyl halides and nitriles is an asynchronous cycloaddition reaction.

Funder

Russian Science Foundation

Fundação para a Ciência e a Tecnologia

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CE/D3CE00385J

Reference61 articles.

1. Synthesis of Heterocycles via Palladium-Catalyzed Carbonylations

2. Synthesis of Oxygen- and Nitrogen-Containing Heterocycles by Ring-Closing Metathesis