Metal-free TBHP-mediated oxidative ring openings of 2-arylimidazopyridines via regioselective cleavage of C–C and C

Metal-free TBHP-mediated oxidative ring openings of 2-arylimidazopyridines via regioselective cleavage of C–C and C–N bonds

Published:2015 Issue:121 Volume:5 Page:100102-100105
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Yan Kelu¹²³⁴⁵,Yang Daoshan¹²³⁴⁵,Wei Wei¹²³⁴⁵,Li Guoqing¹²³⁴⁵,Sun Mingyang¹²³⁴⁵,Zhang Qingyun¹²³⁴⁵,Tian Laijin¹²³⁴⁵,Wang Hua¹²³⁴⁵

Affiliation:

1. The Key Laboratory of Life-Organic Analysis

2. Key Laboratory of Pharmaceutical Intermediates and Analysis of Natural Medicine

3. School of Chemistry and Chemical Engineering

4. Qufu Normal University

5. Qufu 273165

Abstract

A highly regioselective TBHP-mediated ring opening of imidazopyridinesviacleavage of C–C and C–N bonds has been realized for the first time to afford usefulN-(pyridin-2-yl)benzamides under mild conditions.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA17740E

Reference59 articles.

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