Structural insights into hybrid immiscible blends of metal–organic framework and sodium ultraphosphate glasses

Author:

Chester Ashleigh M.1,Castillo-Blas Celia1,Sajzew Roman2ORCID,Rodrigues Bruno P.2ORCID,Mas-Balleste Ruben34ORCID,Moya Alicia3,Snelson Jessica E.5ORCID,Collins Sean M.5ORCID,Sapnik Adam F.1ORCID,Robertson Georgina P.16,Irving Daniel J. M.6ORCID,Wondraczek Lothar2ORCID,Keen David A.7ORCID,Bennett Thomas D.1ORCID

Affiliation:

1. Department of Materials Science and Metallurgy, University of Cambridge, Cambridge, CB3 0FS, UK

2. Otto Schott Institute Materials Research, University of Jena, Fraunhoferstrasse 6, 07743 Jena, Germany

3. Department of Inorganic Chemistry, Universidad Autónoma de Madrid, 28049, Madrid, Spain

4. Institute for Advanced Research in Chemical Sciences (IAdChem), Universidad Autónoma de Madrid, 28049, Madrid, Spain

5. School of Chemical and Process Engineering, School of Chemistry, Bragg Centre for Materials Research, University of Leeds, Woodhouse Lane, LS2 9JT, UK

6. Diamond Light Source Ltd, Diamond House, Harwell Campus, Didcot, Oxfordshire OX11 0DE, UK

7. ISIS Facility, Rutherford Appleton Laboratory, Harwell Campus, Didcot, Oxfordshire OX11 0QX, UK

Abstract

The characterisation of hybrid blends comprising a metal–organic framework (MOF) glass and a phosphate glass is explored. The mechanical and thermal properties of the blends are studied and interfacial interactions between the phases are analysed.

Funder

Leverhulme Trust

Carl-Zeiss-Stiftung

Royal Society

Engineering and Physical Sciences Research Council

University of Leeds

UK Research and Innovation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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