Al-Doped magnetite encapsulated in mesoporous carbon: a long-lasting Fenton catalyst for CWPO of phenol in a fixed-bed reactor under mild conditions

Author:

Thirumoorthy K.1,Gokulakrishnan B.1,Satishkumar G.1ORCID,Landau M. V.2ORCID,Man M. Wong Chi3ORCID,Oliviero E.3

Affiliation:

1. Advanced Materials and Catalysis Lab, Department of Chemistry, School of Advanced Sciences, Vellore Institute of Technology, Vellore-632014, Tamilnadu, India

2. Blechner Center for Industrial Catalysis and Process Development, Department of Chemical Engineering, Ben-Gurion University of the Negev, Beer-Sheva, 84105, Israel

3. ICGM, University of Montpellier, CNRS, ENSCM, Montpellier, France

Abstract

Al substituted magnetite was identified as a promising heterogeneous Fenton catalyst for CWPO of 200 ppm phenol in a continuous system under mild conditions (pH 5, 40 °C, 0.1 ml min−1, 1.2S H2O2) for 500 h with 80% TOC conversion, 1 ppm Fe leaching.

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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