N-Heterocyclic carbene rhodium(i) complexes containing an axis of chirality: dynamics and catalysis-Reference-Cited by-同舟云学术

N-Heterocyclic carbene rhodium(i) complexes containing an axis of chirality: dynamics and catalysis

Published:2014 Issue:4 Volume:38 Page:1768-1779
ISSN:1144-0546
Container-title:New J. Chem.
language:en
Short-container-title:New J. Chem.

Author:

Cassani Maria Cristina¹²,Brucka Marta Anna¹²,Femoni Cristina¹²,Mancinelli Michele¹²,Mazzanti Andrea¹²,Mazzoni Rita¹²,Solinas Gavino¹²

Affiliation:

1. Dipartimento di Chimica Industriale “Toso-Montanari”

2. I-40136 Bologna, Italy

Abstract

Novel rhodium(i) complexes [RhCl(NBD)(NHC)] [NHC = 1-benzyl-3-R-imidazolin-2-ylidene; R = Me, Bz, Tr, ^tBu]: determination of the rotation barriers about the Rh-carbene and catalytic activity in the hydrosilylation of terminal alkynes.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2014/NJ/C3NJ01620J

Reference65 articles.

1. Synthesis and Application of Water-Soluble NHC Transition-Metal Complexes

2. Synthetic Routes to N-Heterocyclic Carbene Precursors

3. Beyond catalysis: N-heterocyclic carbene complexes as components for medicinal, luminescent, and functional materials applications

4. N-Heterocyclic Carbenes in Late Transition Metal Catalysis

5. Understanding the M(NHC) (NHC=N-heterocyclic carbene) bond

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