Single-molecule imaging and kinetic analysis of intermolecular polyoxometalate reactions

Author:

Jordan Jack W.1234ORCID,Fung Kayleigh L. Y.1234ORCID,Skowron Stephen T.1234ORCID,Allen Christopher S.56748ORCID,Biskupek Johannes9101112,Newton Graham N.132144ORCID,Kaiser Ute9101112,Khlobystov Andrei N.1234ORCID

Affiliation:

1. School of Chemistry

2. University of Nottingham

3. Nottingham NG7 2RD

4. UK

5. Electron Physical Science Imaging Center

6. Diamond Light Source Ltd.

7. Didcot OX11 0DE

8. Department of Materials, University of Oxford

9. Electron Microscopy Group of Materials Science

10. Ulm University

11. 89081 Ulm

12. Germany

13. GSK Carbon Neutral Laboratories for Sustainable Chemistry

14. Nottingham NG7 2TU

Abstract

We induce and study reactions of polyoxometalate (POM) molecules, [PW12O40]3− (Keggin) and [P2W18O62]6− (Wells–Dawson), at the single-molecule level, utilising TEM as an analytical tool, and nanotubes as test tubes.

Funder

Engineering and Physical Sciences Research Council

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference72 articles.

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2. L. J. P.Atkins , Chemical Principles: The Quest for Insight , W. H. Freeman & Co , N.Y. , 2nd edn, 2002

3. Does phenomenological kinetics provide an adequate description of heterogeneous catalytic reactions?

4. Stochastic chemical kinetics

5. Handbook of Single-Molecule Biophysics , Springer-Verlag , New York , 1 edn, 2009

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